Search results for "chemistry [Arsenates]"
showing 10 items of 2372 documents
Occurrence of fossil organic matter in modern environments: optical, geochemical and isotopic evidence
2011
International audience; This study relates to the input and fate of fossil organic matter (FOM) in the modern environment, and focuses on two experimental watersheds overlying Jurassic marls: Le Laval and Le Brusquet (1 km(2) in area), located near Digne, Alpes-de-Haute-Provence, France. Considering that FOM delivery is mainly a result of different processes affecting sedimentary rocks [(bio)chemical and mechanical weathering], samples from different pools were collected: bedrocks, weathering profiles, soils and riverine particles. The samples were examined using complementary techniques: optical (palynofacies methods), geochemical (Rock-Eval 6 pyrolysis, C/N ratio), molecular (gas chromato…
Chlorine Partitioning Between a Basaltic Melt and H2O-CO2 Fluids at Mount Etna
2009
Partitioning experiments between a basaltic melt from Mt. Etna and a low-density hydrous fluid or vapor containing H(2)O or H(2)O-CO(2) were performed at 1200-1260 degrees C, at pressures between 1 and 200 MPa, either near the nickel-nickel oxide (NNO) buffer or at two log units above it (NNO + 2), and with different chloride concentrations. Most of the experiments were done at chloride-brine-undersaturated conditions, although at the highest Cl concentrations explored brine saturation might have been reached. The average partition coefficients (D(Cl)(fluid/melt)) over the range of Cl concentrations were derived on a weight basis by plotting the calculated concentrations of Cl in the fluid …
Seafloor expression of oceanic detachment faulting reflects gradients in mid-ocean ridge magma supply
2019
International audience; Oceanic detachment faulting is a major mode of seafloor accretion at slow and ultraslow spreading mid-ocean ridges, and is associated with dramatic changes in seafloor morphology. Detachments form expansive dome structures with corrugated surfaces known as oceanic core complexes (OCCs), and often transition to multiple regularly-spaced normal faults that form abyssal hills parallel to the spreading axis. Previous studies have attributed these changes to along-axis gradients in lithospheric strength or magma supply. However, despite the recognition that magma supply can influence fault style and seafloor morphology, the mechanics controlling the transition from oceani…
Growth of stylolite teeth patterns depending on normal stress and finite compaction
2007
Abstract Stylolites are spectacular rough dissolution surfaces that are found in many rock types. They are formed during a slow irreversible deformation in sedimentary rocks and therefore participate to the dissipation of tectonic stresses in the Earth's upper crust. Despite many studies, their genesis is still debated, particularly the time scales of their formation and the relationship between this time and their morphology. We developed a new discrete simulation technique to explore the dynamic growth of the stylolite roughness, starting from an initially flat dissolution surface. We demonstrate that the typical steep stylolite teeth geometry can accurately be modelled and reproduce natu…
Modelling of stylolite geometries and stress scaling
2012
International audience; In this contribution we present numerical simulations of stylolite growth to decipher the effects of initial rock heterogeneity and stress on their morphology. We show that stylolite growth in a rock with a uniform grain size produces different patterns than stylolite growth in a rock with a bimodal grain size distribution. Strong pinning of large heterogeneities produce stylolite structures that are dominated by pronounced teeth, whereas a uniform grain size leads to spikes and a roughness that shows variable wavelengths. We compare the simulated stylolites with natural examples and show that the model can reproduce the real structures. In addition we show that stro…
Trace element behaviour in seawater during Etna's pyroclastic activity in 2001: Concurrent effects of nutrients and formation of alteration minerals
2010
volcanic ash ; trace element leaching ; kinetic experiments ; chlorophyll-alpha; International audience; The eruption of Etna in Sicily on 13 July 2001 marked the most intense activity of the volcano in the last 300 years. The eruption occurred while the oceanographic cruise ANSIC 01 was being conducted to the east of Sicily, presenting a unique opportunity for the investigation of the chemical effects on the marine system during a period of significant (similar to 1 g m(-2)) ash deposition. Comparison of trace element data with measured concentrations from the oceanographic cruise JUVENILE 99, carried out two years before, indicates large enrichments of V. Cr, Mn, Fe, Co, Cu and Pb. We att…
Textural-chemical changes and deformation conditions registered by phyllosilicates in a fault zone (Pic de Port Vieux thrust, Pyrenees)
2017
International audience; Synkinematic phyllosilicates in fault zones can be used to deduce the deformation mechanisms and the conditions of fault activity, as their chemical composition, crystal structure and texture can record the different stages of deformation and fluid-rock interactions. The Pic de Port Vieux, a second-order thrust related to the major Gavarnie thrust in the southern central part of the Pyrenees Axial Zone, juxtaposes Triassic pelites of the hanging wall and Cretaceous limestones of the footwall. In order to investigate the mineralogical and geochemical changes and constrain the deformation conditions of thrusting, characterization of phyllosilicates was performed along …
Was climatic cooling during the earliest Carboniferous driven by expansion of seed plants?
2021
Abstract The expansion of land plants is considered to have played a key role in triggering the Late Paleozoic Ice Age (LPIA), but evidence linking climatic events to terrestrial floral changes is limited. Here, we generated bulk carbonate δ13C, conodont δ18O and 87Sr/86Sr profiles from the lowermost Carboniferous of South China and Vietnam in order to investigate their relationship to contemporaneous land plant evolution. Climatic cooling in the mid-Tournaisian coincided with large perturbations to the global carbon cycle and continental weathering regimes as well as with a major diversification episode among seed plants. These relationships are consistent with terrestrial floral changes t…
A sugar biomarker proxy for assessing terrestrial versus aquatic sedimentary input
2016
Abstract One of the most important and at the same time most challenging issues in paleolimnological research is the differentiation between terrestrial and aquatic sedimentary organic matter (OM). We therefore investigated the relative abundance of the sugars fucose (fuc), arabinose (ara) and xylose (xyl) from various terrestrial and aquatic plants, as well as from algal samples. Algae were characterized by a higher abundance of fucose than vascular plants. Our results and a compilation of data from the literature suggest that fuc/(ara + xyl) and (fuc + xyl)/ara ratios may serve as complementary proxies in paleolimnological studies for distinguishing between terrestrial and aquatic sedimen…
Decrespignyite-(Y), a new copper yttrium rare earth carbonate chloride hydrate from Paratoo, South Australia
2002
AbstractDecrespignyite-(Y) is a new copper yttrium rare earth carbonate chloride hydrate from the Paratoo copper mine, near Yunta, Olary district, South Australia. Decrespignyite-(Y) occurs as blue crusts, coatings and fillings in thin fissures on the slatey country rock. Individual pseudohexagonal platelets are typically 10–50 µm in maximum dimension and are often curved. Associated minerals include caysichite-(Y), donnayite-(Y), malachite and kamphaugite-(Y). Electron microprobe and CHN analyses gave: Y2O3 42.2; La2O3 0.1; Pr2O3 0.1; Nd2O3 1.3; Sm2O3 1.0; Gd2O3 4; Tb2O3 0.4; Dy2O3 3.7; Ho2O3 2.6; Er2O3 2.5; CaO 0.5; CuO 10.9; Cl 3.0; CO2 19.8; H2O 10.8, yielding an empirical formula of (Y…